Ruthenium-catalyzed ortho -C-H mono- and di-imidation of arenes with n -tosyloxyphthalimide
Ruthenium-catalyzed ortho -C-H mono- and di-imidation of arenes with n -tosyloxyphthalimide
| dc.contributor.author | Yadav, M. Ramu | |
| dc.contributor.author | Shankar, Majji | |
| dc.contributor.author | Ramesh, E. | |
| dc.contributor.author | Ghosh, Koushik | |
| dc.contributor.author | Sahoo, Akhila K. | |
| dc.date.accessioned | 2022-03-27T08:33:49Z | |
| dc.date.available | 2022-03-27T08:33:49Z | |
| dc.date.issued | 2015-04-17 | |
| dc.description.abstract | The Ru(II)-catalyzed imidation of the o-C-H bond in arenes with N-tosyloxyphthalimide is realized with the assistance of a methyl phenylsulfoximine (MPS) directing group. This method is applicable to access the hitherto difficult o-C-H di-imidation products. The sequential C-N and C-C bond formation of o-C-H arenes creates peripherally decorated benzoic acid derivatives. The readily removable MPS-DG and easily modifiable phthaloyl moiety make this strategy synthetically viable for constructing highly functionalized C-N bearing arenes and heteroarenes. | |
| dc.identifier.citation | Organic Letters. v.17(8) | |
| dc.identifier.issn | 15237060 | |
| dc.identifier.uri | 10.1021/acs.orglett.5b00570 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.orglett.5b00570 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/10804 | |
| dc.title | Ruthenium-catalyzed ortho -C-H mono- and di-imidation of arenes with n -tosyloxyphthalimide | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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