Synthesis and characterization of a chiral dimeric copper(II) complex: Crystal structure of [Cu < inf > 2 < /inf > (μ-Cl) < inf > 2 < /inf > (HL) < inf > 2 < /inf > ]-H < inf > 2 < /inf > O(H < inf > 2 < /inf > L = S-(-)-2-[(2-hydroxy-1-phenyl- ethylimino)-methyl]-phenol)
Synthesis and characterization of a chiral dimeric copper(II) complex: Crystal structure of [Cu < inf > 2 < /inf > (μ-Cl) < inf > 2 < /inf > (HL) < inf > 2 < /inf > ]-H < inf > 2 < /inf > O(H < inf > 2 < /inf > L = S-(-)-2-[(2-hydroxy-1-phenyl- ethylimino)-methyl]-phenol)
| dc.contributor.author | Pradeep, Chullikkattil P. | |
| dc.contributor.author | Zacharias, Panthapally S. | |
| dc.contributor.author | Das, Samar K. | |
| dc.date.accessioned | 2022-03-27T08:44:30Z | |
| dc.date.available | 2022-03-27T08:44:30Z | |
| dc.date.issued | 2005-01-01 | |
| dc.description.abstract | Synthesis and characterization of an optically active binuclear dichloro-bridged copper(II) complex [Cu2(μ-Cl)2(HL) 2]-H2O 1 (H2L = S-(-)-2-[(2-hydroxy-1-phenyl- ethylimino)-methyl]-phenol) of a Schiff-base derived from salicylaldehyde and (S)-(+)-2-phenylglycinol are described. Compound 1 crystallizes in the orthorhombic chiral P212121 space group with Z = 4, a =10·21(2), b=11·574(3), c = 25·364(9). Each copper shows square pyramidal geometry with O2NCl2 coordination and the Cu2Cl2 core geometry adopts a butterfly shape. Crystals of 1 were further characterized by elemental analysis, IR, UV-visible and EPR spectroscopy and circular dichroism (CD) studies. © Indian Academy of Sciences. | |
| dc.identifier.citation | Journal of Chemical Sciences. v.117(2) | |
| dc.identifier.issn | 02534134 | |
| dc.identifier.uri | 10.1007/bf03356107 | |
| dc.identifier.uri | http://link.springer.com/10.1007/BF03356107 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11660 | |
| dc.subject | Chiral properties | |
| dc.subject | Crystal structure | |
| dc.subject | Dinuclear copper(II) complex | |
| dc.title | Synthesis and characterization of a chiral dimeric copper(II) complex: Crystal structure of [Cu < inf > 2 < /inf > (μ-Cl) < inf > 2 < /inf > (HL) < inf > 2 < /inf > ]-H < inf > 2 < /inf > O(H < inf > 2 < /inf > L = S-(-)-2-[(2-hydroxy-1-phenyl- ethylimino)-methyl]-phenol) | |
| dc.type | Journal. Conference Paper | |
| dspace.entity.type |
Files
License bundle
1 - 1 of 1