Convenient methods for the reduction of amides, nitriles, carboxylic esters, acids and hydroboration of alkenes using NaBH < inf > 4 < /inf > /I < inf > 2 < /inf > system
Convenient methods for the reduction of amides, nitriles, carboxylic esters, acids and hydroboration of alkenes using NaBH < inf > 4 < /inf > /I < inf > 2 < /inf > system
| dc.contributor.author | Prasad, A. S.Bhanu | |
| dc.contributor.author | Kanth, J. V.Bhaskar | |
| dc.contributor.author | Periasamy, Mariappan | |
| dc.date.accessioned | 2022-03-27T09:12:10Z | |
| dc.date.available | 2022-03-27T09:12:10Z | |
| dc.date.issued | 1992-01-01 | |
| dc.description.abstract | Reaction of amides with NaBH4-I2 system in THF gives the corresponding amines in 70-76% yields. Reduction of nitriles yields the corresponding amines in 70-75% yields. The I2/NaBH4 system is useful in the hydrocarboration of olefins and the corresponding alcohols are obtained in 78-92% yields after H2O2/OH- oxidation. The reagent system is also useful for the reduction of carboxylic esters and acids to the corresponding alcohols in 60-90% yields. © 1992. | |
| dc.identifier.citation | Tetrahedron. v.48(22) | |
| dc.identifier.issn | 00404020 | |
| dc.identifier.uri | 10.1016/S0040-4020(01)81236-9 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0040402001812369 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12577 | |
| dc.title | Convenient methods for the reduction of amides, nitriles, carboxylic esters, acids and hydroboration of alkenes using NaBH < inf > 4 < /inf > /I < inf > 2 < /inf > system | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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