Meso-Free Boron(III)subchlorin and Its μ-Oxo Dimer with Interacting Chromophores
Meso-Free Boron(III)subchlorin and Its μ-Oxo Dimer with Interacting Chromophores
| dc.contributor.author | Chandra, Brijesh | |
| dc.contributor.author | Soman, Rahul | |
| dc.contributor.author | Sathish Kumar, B. | |
| dc.contributor.author | Jose, K. V.Jovan | |
| dc.contributor.author | Panda, Pradeepta K. | |
| dc.date.accessioned | 2022-03-27T08:37:44Z | |
| dc.date.available | 2022-03-27T08:37:44Z | |
| dc.date.issued | 2020-12-18 | |
| dc.description.abstract | Meso-free B(III)subchlorin 1 has been realized exclusively for the first time from meso-ethoxycarbonyl-substituted tripyrrane along with the first subchlorin dimer 2 as its μ-oxo analogue via a facile one-pot approach. The subchlorin is highly stable toward oxidation; hence, it was not contaminated with the corresponding subporphyrin analogue 3. The subchlorin (56%) and its dimer (30%) exhibit singlet oxygen generation ability for the first time. The B-O-B dimer displays strong exciton coupling between the two macrocycles. | |
| dc.identifier.citation | Organic Letters. v.22(24) | |
| dc.identifier.issn | 15237060 | |
| dc.identifier.uri | 10.1021/acs.orglett.0c03813 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.orglett.0c03813 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11275 | |
| dc.title | Meso-Free Boron(III)subchlorin and Its μ-Oxo Dimer with Interacting Chromophores | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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