Organo-oxotin cages containing arsinate ligands
Organo-oxotin cages containing arsinate ligands
| dc.contributor.author | Burton, S. D. | |
| dc.contributor.author | Swamy, K. C.Kumara | |
| dc.contributor.author | Holmes, R. R. | |
| dc.contributor.author | Day, R. O. | |
| dc.date.accessioned | 2022-03-27T10:00:07Z | |
| dc.date.available | 2022-03-27T10:00:07Z | |
| dc.date.issued | 1989-02-01 | |
| dc.description.abstract | New monoorgano-oxotin cages which possess bridging arsinate ligands have been prepared and characterized by X-ray and 119Sn NMR spectroscopy. The tetrameric, trimeric, and dimeric tin compounds containing arsinate ligands and six and four-membered stannoxane rings exhibit characteristics which parallel the phosphinate-bridged cages previously reported.1,2 Conversion of the tetrameric cube structure, [n-BuSn0(O2AsMe2)]4, to a mixed butterfly composition is easily accomplished by addition of arsinic, phosphinic, or carboxylic acid. For example, two butterfly compounds that we formed are: [n-BuSn(OH)(O2AsMe2)(OP(O)Me2)]2 and [n-BuSn(OH)(O2AsMe2)(OAs(O)Me2)]2. © 1989, Taylor & Francis Group, LLC. All rights reserved. | |
| dc.identifier.citation | Phosphorus, Sulfur, and Silicon and the Related Elements. v.41(3-4) | |
| dc.identifier.issn | 10426507 | |
| dc.identifier.uri | 10.1080/10426508908039746 | |
| dc.identifier.uri | http://www.tandfonline.com/doi/abs/10.1080/10426508908039746 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13514 | |
| dc.title | Organo-oxotin cages containing arsinate ligands | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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