Asymmetric reduction of prochiral aromatic ketones by Borane-Amine complexes in the presence of a chiral amine-BF < inf > 3 < /inf > catalyst
Asymmetric reduction of prochiral aromatic ketones by Borane-Amine complexes in the presence of a chiral amine-BF < inf > 3 < /inf > catalyst
| dc.contributor.author | Kanth, J. V.Bhaskar | |
| dc.contributor.author | Periasamy, Mariappan | |
| dc.date.accessioned | 2022-03-27T09:12:29Z | |
| dc.date.available | 2022-03-27T09:12:29Z | |
| dc.date.issued | 1990-12-01 | |
| dc.description.abstract | The (-)-N-α-Methylbenzyl-3,5-dihydrodinaphthazepine-BH3 complex reduces aromatic ketones to alcohols with 11-57% enantiomeric excess (e.e.) in the presence of BF3·OEt2, the (-)-N-α-methylbenzyl-3,5 dihydrodinaphthazepine-BF3 complex catalyses asymmetric reduction of acetophenone by N,N′-diethylaniline- BH3 to give α-phenylethyl alcohol in 51% e.e. | |
| dc.identifier.citation | Journal of the Chemical Society, Chemical Communications | |
| dc.identifier.issn | 00224936 | |
| dc.identifier.uri | 10.1039/C39900001145 | |
| dc.identifier.uri | http://xlink.rsc.org/?DOI=C39900001145 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12585 | |
| dc.title | Asymmetric reduction of prochiral aromatic ketones by Borane-Amine complexes in the presence of a chiral amine-BF < inf > 3 < /inf > catalyst | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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