Efficient Synthesis of Functionalized β-Keto Esters and β-Diketones through Regioselective Hydration of Alkynyl Esters and Alkynyl Ketones by Use of a Cationic NHC–Au < sup > I < /sup > Catalyst

dc.contributor.author	Tarigopula, Chandrahas
dc.contributor.author	Thota, Ganesh Kumar
dc.contributor.author	Balamurugan, Rengarajan
dc.date.accessioned	2022-03-27T08:39:12Z
dc.date.available	2022-03-27T08:39:12Z
dc.date.issued	2016-12-01
dc.description.abstract	Regioselective hydration of α-alkynyl esters and ketones by using a cationic NHC–AuIcatalyst results in β-keto esters and β-diketones, respectively. Controlled release of water in acetone by aldol self-condensation under the reaction conditions makes acetone as better solvent than 1,4-dioxane/water for the hydration of α-alkynyl esters having sensitive ester moieties.
dc.identifier.citation	European Journal of Organic Chemistry. v.2016(35)
dc.identifier.issn	1434193X
dc.identifier.uri	10.1002/ejoc.201601025
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/ejoc.201601025
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11374
dc.subject	Alkynes
dc.subject	Gold
dc.subject	Homogeneous catalysis
dc.subject	Hydration
dc.subject	β-Diketones
dc.subject	β-Keto esters
dc.title	Efficient Synthesis of Functionalized β-Keto Esters and β-Diketones through Regioselective Hydration of Alkynyl Esters and Alkynyl Ketones by Use of a Cationic NHC–Au < sup > I < /sup > Catalyst
dc.type	Journal. Article
dspace.entity.type

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