Effect of β-β′ Fusion on metal ion complexation of porphycene
Effect of β-β′ Fusion on metal ion complexation of porphycene
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Date
2015-02-01
Authors
Sarma, Tridib
Panda, Pradeepta K.
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Abstract
Complexation of β - β ′ fused π-extended porphycene, namely dinaphthoporphycene was carried out successfully with copper(II) and its solid state structure shows a square-type planar N4-coordination core. The photophysical and electrochemical properties of this complex, along with the nickel(II) complex were also investigated. Further, electronic paramagnetic resonance (EPR) analysis of this complex is also reported.
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Keywords
Porphycene,
porphycene complexation,
porphyrin isomer,
square-type-coordination.,
β - β ′ fused porphycene,
π-extended porphycene
Citation
Journal of Chemical Sciences. v.127(2)