A diruthenum(III) complex possessing a diazine and two chloride bridges: Synthesis, structure, and properties
A diruthenum(III) complex possessing a diazine and two chloride bridges: Synthesis, structure, and properties
No Thumbnail Available
Date
2001-08-27
Authors
Pal, S.
Pal, S.
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
A dinuclear Ru(III) complex, [Ru2Cl2(PPh3)2(μ-Cl) 2-(μ-salhn)], has been synthesized and characterized by analytical, spectroscopic, magnetic, and X-ray diffractometry. The redox active complex displays two reductions corresponding to RuIII2/RuIIIRuII and RuIII-RuIIRuII2 couples. A weak antiferromagnetic spin coupling is operative between the two low-spin Ru(III) centers.
Description
Keywords
Citation
Inorganic Chemistry. v.40(18)