Sulfoximines: A reusable directing group for chemo-and regioselective ortho C-H oxidation of arenes

dc.contributor.author	Yadav, M. Ramu
dc.contributor.author	Rit, Raja K.
dc.contributor.author	Sahoo, Akhila K.
dc.date.accessioned	2022-03-27T08:34:49Z
dc.date.available	2022-03-27T08:34:49Z
dc.date.issued	2012-04-27
dc.description.abstract	Sulfoximines direct: A new protocol for the chemo-and regioselective ortho C-H acetoxylation of arenes in N-benzoylated sulfoximines is reported. The sulfoximine directing group is easily detached from the C-H oxidation product through acid-promoted hydrolysis, isolated, and reused (see scheme). The meta-substituted phenols are synthesized following this strategy and the stereointegrity of the sulfoximine is preserved in this transformation. C(sp 3)-H acetoxylation of the methyl group is also demonstrated. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.identifier.citation	Chemistry - A European Journal. v.18(18)
dc.identifier.issn	09476539
dc.identifier.uri	10.1002/chem.201200092
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/chem.201200092
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/10993
dc.subject	C-H activation
dc.subject	directing group
dc.subject	oxidation
dc.subject	regioselectivity
dc.subject	sulfoximines
dc.title	Sulfoximines: A reusable directing group for chemo-and regioselective ortho C-H oxidation of arenes
dc.type	Journal. Article
dspace.entity.type

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