A simple TiCl < inf > 4 < /inf > promoted arylation of orthoformate and benzyl ethers by N,N-dialkylarylamines
A simple TiCl < inf > 4 < /inf > promoted arylation of orthoformate and benzyl ethers by N,N-dialkylarylamines
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Date
2007-03-12
Authors
Periasamy, Mariappan
Kishorebabu, Neela
Natarajan Jayakumar, K.
Journal Title
Journal ISSN
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Abstract
N,N-Dialkylarylamines react with trimethyl orthoformate and TiCl4 under ambient conditions to give the corresponding formyl derivatives in 75-89% yields, whereas the corresponding arylated products are obtained from benzyl ethers and acetals in 42-78% yields. © 2007.
Description
Keywords
Formylation,
N,N-Dialkylarylamines,
Titanium tetrachloride,
Trimethyl orthoformate
Citation
Tetrahedron Letters. v.48(11)