Solventless Reactions for the Synthesis of Organotin Clusters and Cages
Solventless Reactions for the Synthesis of Organotin Clusters and Cages
| dc.contributor.author | Chandrasekhar, Vadapalli | |
| dc.contributor.author | Baskar, Viswanathan | |
| dc.contributor.author | Boomishankar, Ramamoorthy | |
| dc.contributor.author | Gopal, Kandasamy | |
| dc.contributor.author | Zacchini, Stefano | |
| dc.contributor.author | Bickley, Jamie F. | |
| dc.contributor.author | Steiner, Alexander | |
| dc.date.accessioned | 2022-03-27T09:00:31Z | |
| dc.date.available | 2022-03-27T09:00:31Z | |
| dc.date.issued | 2003-09-01 | |
| dc.description.abstract | Organotin clusters and cages have been synthesized in quantitative yields by using a benign solventless synthetic methodology. Using this method a variety of structural forms, which include the drum, O-capped cluster, tetranuclear oxo cage, discrete, and polymeric compounds, have been synthesized. All these compounds (1-11) have been characterized by spectroscopic and analytical techniques. The new compounds, which include the hexameric drum [n-BuSn(O)OCOAd]6 (Ad = adamantyl) 9, a triorganotin-based discrete structure Ph3SnO2C-C6-H 22,4,6-Me3 (10), and a polymer Ph3SnOSO 2-C6H3-2,5-Me2 (11), have been characterized by single-crystal X-ray crystallography. | |
| dc.identifier.citation | Organometallics. v.22(18) | |
| dc.identifier.issn | 02767333 | |
| dc.identifier.uri | 10.1021/om030338c | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/om030338c | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12256 | |
| dc.title | Solventless Reactions for the Synthesis of Organotin Clusters and Cages | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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