New addition and cyclization reactions involving phosphorus based allenes

dc.contributor.author	Swamy, K. C.Kumara
dc.contributor.author	Pavan, M. Phani
dc.contributor.author	Anitha, Mandala
dc.contributor.author	Gangadhararao, G.
dc.date.accessioned	2022-03-27T09:47:59Z
dc.date.available	2022-03-27T09:47:59Z
dc.date.issued	2018-02-01
dc.description.abstract	In this paper, we describe convenient methods for functionally active phenol addition reaction of allenylphosphonates/allenyl phosphine oxides. These reactions lead to either vinyl or allylphosphonates. In the reaction α-aryl allenylphosphonates with 2-iodophenol in the presence of Pd nanoparticles [Pd-PVP] isomeric vinylphosphonates are preferentially obtained. A novel cyclization reaction of 2-iodo-t-butylbenzaldimine with and allenylphosphine oxide that leads to an isoquinoline is also discovered; the product is characterized by single crystal X-ray structure determination.
dc.identifier.citation	Phosphorus, Sulfur and Silicon and the Related Elements. v.193(2)
dc.identifier.issn	10426507
dc.identifier.uri	10.1080/10426507.2017.1417302
dc.identifier.uri	https://www.tandfonline.com/doi/full/10.1080/10426507.2017.1417302
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/13317
dc.subject	Allenes
dc.subject	Allenylphosphine oxides
dc.subject	Allenylphosphonates
dc.subject	Cyclization
dc.subject	Nucleophilic addition
dc.title	New addition and cyclization reactions involving phosphorus based allenes
dc.type	Journal. Article
dspace.entity.type

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