Redox shield enfolding a magnetic core
Redox shield enfolding a magnetic core
| dc.contributor.author | Kishore, Pilli V.V.N. | |
| dc.contributor.author | Rasamsetty, Amaleswari | |
| dc.contributor.author | Carolina Sañudo, E. | |
| dc.contributor.author | Baskar, Viswanathan | |
| dc.date.accessioned | 2022-03-27T08:59:35Z | |
| dc.date.available | 2022-03-27T08:59:35Z | |
| dc.date.issued | 2015-12-14 | |
| dc.description.abstract | Ferrocenyl betadiketones were reacted with hydrated lanthanide trihalides in presence of a base to yield red color solids, whose structures were characterized by single crystal X-ray diffraction technique. Structural analysis revealed the formation of nona- and tetranuclear lanthanide oxo-hydroxo clusters [Dy9(μ4-O)2(μ3-OH)8(μ-Fca)8(Fca)8]-[HN(C2H5)3]+ (1), [Ln4(μ-OH)2(μ-OCH3)4(CH3OH)2(Fctfa)6] Ln = Yb (2), Lu (3), and [Ln4(μ-OH)2(μ-OCH3)4(CH3OH)2(Fcpfa)6] Ln = Yb (4), Lu (5). Magnetism studies revealed that 1 shows slow relaxation of magnetisation. Cyclic voltammetry studies of 1 reveal electrochemically stable quasi reversible oxidation systems whereas 2-5 showed irreversible nature. | |
| dc.identifier.citation | Polyhedron. v.102 | |
| dc.identifier.issn | 02775387 | |
| dc.identifier.uri | 10.1016/j.poly.2015.10.017 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0277538715005987 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12227 | |
| dc.subject | Beta-diketones | |
| dc.subject | Lanthanide oxo-hydroxo clusters | |
| dc.subject | Multi ferrocenes | |
| dc.subject | Self-assembly | |
| dc.subject | Slow relaxation of magnetization | |
| dc.title | Redox shield enfolding a magnetic core | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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