Cyclization and Cycloisomerization of π-Tethered Ynamides: An Expedient Synthetic Method to Construct Carbo- and Heterocycles

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dc.contributor.author Prabagar, B.
dc.contributor.author Ghosh, Nayan
dc.contributor.author Sahoo, Akhila K.
dc.date.accessioned 2022-03-27T09:51:58Z
dc.date.available 2022-03-27T09:51:58Z
dc.date.issued 2017-12-01
dc.description.abstract Stable ynamides are used for the development of novel synthetic transformations and the construction of unusual carbo/heterocycles. The intramolecular cyclization of π-tethered alkene/alkyne/allene-ynamides is studied extensively for the fabrication of a wide range of molecular scaffolds for various applications. The ketene-acetal/aminal generated in situ from π-tethered ynamides participates in intramolecular cyclization/cycloisomerization processes to yield N-bearing fused heterocycles. This account summarizes the scientific merits and the advances made in cyclization and cycloisomerization strategies for stable π-tethered alkene/alkyne/allene-ynamides. 1 Introduction 2 π-Tethered Ynamides 3 Alkene-Tethered Ynamides 4 Alkyne-Tethered Ynamides 5 Allene-Tethered Ynamides 6 Concluding Remarks.
dc.identifier.citation Synlett. v.28(19)
dc.identifier.issn 09365214
dc.identifier.uri 10.1055/s-0036-1590877
dc.identifier.uri http://www.thieme-connect.de/DOI/DOI?10.1055/s-0036-1590877
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/13385
dc.subject carbenes
dc.subject cycloaddition
dc.subject cycloisomerization
dc.subject cyclopropanation
dc.subject heterocycles
dc.subject radical cyclization
dc.subject ring-closing metathesis
dc.subject ynamides
dc.title Cyclization and Cycloisomerization of π-Tethered Ynamides: An Expedient Synthetic Method to Construct Carbo- and Heterocycles
dc.type Journal. Article
dspace.entity.type
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