Regioselective hydration of terminal halo-substituted propargyl carboxylates by gold catalyst: Synthesis of α-acyloxy α'-halo ketones

dc.contributor.author Ghosh, Nayan
dc.contributor.author Nayak, Sanatan
dc.contributor.author Prabagar, B.
dc.contributor.author Sahoo, Akhila K.
dc.date.accessioned 2022-03-27T08:34:06Z
dc.date.available 2022-03-27T08:34:06Z
dc.date.issued 2014-03-21
dc.description.abstract Regioselective hydration of the terminal halo-substituted propargyl carboxylate by gold(I) catalyst is reported. The mild catalytic conditions tolerate common acid-labile protecting groups, and a wide variety of α-acyloxy α'-halo ketones are efficiently synthesized within a short reaction time. The α-acyloxy α'-halo ketones are used for the synthesis of 2-aminothiazoles. © 2014 American Chemical Society.
dc.identifier.citation Journal of Organic Chemistry. v.79(6)
dc.identifier.issn 00223263
dc.identifier.uri 10.1021/jo4027319
dc.identifier.uri https://pubs.acs.org/doi/10.1021/jo4027319
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/10871
dc.title Regioselective hydration of terminal halo-substituted propargyl carboxylates by gold catalyst: Synthesis of α-acyloxy α'-halo ketones
dc.type Journal. Article
dspace.entity.type
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