(5S)-1,3-Diaza-2-imino-3-phenylbicyclo[3.3.0]octane: first example of guanidine based in situ recyclable chiral catalytic source for borane-mediated asymmetric reduction of prochiral ketones
(5S)-1,3-Diaza-2-imino-3-phenylbicyclo[3.3.0]octane: first example of guanidine based in situ recyclable chiral catalytic source for borane-mediated asymmetric reduction of prochiral ketones
| dc.contributor.author | Basavaiah, Deevi | |
| dc.contributor.author | Venkateswara Rao, Kalapala | |
| dc.contributor.author | Sekhara Reddy, Bhavanam | |
| dc.date.accessioned | 2022-03-27T09:02:11Z | |
| dc.date.available | 2022-03-27T09:02:11Z | |
| dc.date.issued | 2006-04-03 | |
| dc.description.abstract | (5S)-1,3-Diaza-2-imino-3-phenylbicyclo[3.3.0]octane has been synthesized and successfully employed, for the first time, as a chiral catalytic source for the borane-mediated asymmetric reduction of prochiral α-halo ketones to provide the corresponding secondary alcohols in high enantiomeric purity. The potential of this guanidine as an in situ recyclable chiral catalytic source for the borane-mediated chiral reduction processes has also been demonstrated. © 2006 Elsevier Ltd. All rights reserved. | |
| dc.identifier.citation | Tetrahedron Asymmetry. v.17(7) | |
| dc.identifier.issn | 09574166 | |
| dc.identifier.uri | 10.1016/j.tetasy.2006.03.020 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0957416606001996 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12306 | |
| dc.title | (5S)-1,3-Diaza-2-imino-3-phenylbicyclo[3.3.0]octane: first example of guanidine based in situ recyclable chiral catalytic source for borane-mediated asymmetric reduction of prochiral ketones | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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