The reaction of allenes with phosphorus(III) compounds bearing a P-NH-(t-Bu) group: isolation of both enantiomers in crystalline form from an achiral system
The reaction of allenes with phosphorus(III) compounds bearing a P-NH-(t-Bu) group: isolation of both enantiomers in crystalline form from an achiral system
| dc.contributor.author | Bhuvan Kumar, N. N. | |
| dc.contributor.author | Kumara Swamy, K. C. | |
| dc.date.accessioned | 2022-03-27T09:52:34Z | |
| dc.date.available | 2022-03-27T09:52:34Z | |
| dc.date.issued | 2008-12-08 | |
| dc.description.abstract | Structural characterization of the tautomeric forms of the zwitterions proposed in the phosphine catalyzed transformations of electron-deficient allenes by utilizing a cyclodiphosphazane with a P-NH-t-Bu group and Ph2P(NH-t-Bu) is described. Spontaneous resolution of the products (R and S enantiomers of the crystals) via crystallization is highlighted. © 2008 Elsevier Ltd. All rights reserved. | |
| dc.identifier.citation | Tetrahedron Letters. v.49(50) | |
| dc.identifier.issn | 00404039 | |
| dc.identifier.uri | 10.1016/j.tetlet.2008.09.153 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0040403908018340 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13395 | |
| dc.title | The reaction of allenes with phosphorus(III) compounds bearing a P-NH-(t-Bu) group: isolation of both enantiomers in crystalline form from an achiral system | |
| dc.type | Journal. Article | |
| dspace.entity.type |
Files
License bundle
1 - 1 of 1