Sulfinyl group as an intramolecular nucleophile: Synthesis of bromohydrins from β-methyl-γ,δ-unsaturated sulfoxides with high 1,2-asymmetric induction
Sulfinyl group as an intramolecular nucleophile: Synthesis of bromohydrins from β-methyl-γ,δ-unsaturated sulfoxides with high 1,2-asymmetric induction
| dc.contributor.author | Raghavan, Sadagopan | |
| dc.contributor.author | Reddy, S. Ramakrishna | |
| dc.contributor.author | Tony, K. A. | |
| dc.contributor.author | Kumar, Ch Naveen | |
| dc.contributor.author | Varma, Ashok K. | |
| dc.contributor.author | Nangia, Ashwini | |
| dc.date.accessioned | 2022-03-27T09:32:14Z | |
| dc.date.available | 2022-03-27T09:32:14Z | |
| dc.date.issued | 2002-08-09 | |
| dc.description.abstract | Bromohydrins have been prepared from β-methyl-γ,δ-unsaturated sulfoxides with high regio- and stereoselectivity. The reaction proceeds via neighboring group participation of the sulfinyl moiety with inversion of sulfoxide configuration as proven by an 18O labeling study and x-ray crystallography. | |
| dc.identifier.citation | Journal of Organic Chemistry. v.67(16) | |
| dc.identifier.issn | 00223263 | |
| dc.identifier.uri | 10.1021/jo015921m | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/jo015921m | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13025 | |
| dc.title | Sulfinyl group as an intramolecular nucleophile: Synthesis of bromohydrins from β-methyl-γ,δ-unsaturated sulfoxides with high 1,2-asymmetric induction | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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