Convenient procedures for the asymmetric reductions utilizing α,α-diphenyl- pyrrolidinemethanol and borane complexes generated using the I < inf > 2 < /inf > /NaBH < inf > 4 < /inf > system
Convenient procedures for the asymmetric reductions utilizing α,α-diphenyl- pyrrolidinemethanol and borane complexes generated using the I < inf > 2 < /inf > /NaBH < inf > 4 < /inf > system
| dc.contributor.author | Periasamy, Mariappan | |
| dc.contributor.author | Kanth, J. V.Bhaskar | |
| dc.contributor.author | Prasad, A. S.Bhanu | |
| dc.date.accessioned | 2022-03-27T09:11:44Z | |
| dc.date.available | 2022-03-27T09:11:44Z | |
| dc.date.issued | 1994-01-01 | |
| dc.description.abstract | Syntheses of oxazaborolidine in situ in benzene using α,α-diphenylpyrrolidinemethanol and diborane, generated from the iodine-sodium borohydride system are described. The oxazaboro- lidine (10 mole%), generated by the reaction of α,α-diphenylpyrrolidinemethanol and diborane in benzene followed by heating with N,N-diethylaniline, in combination with boranetetrahydrofuran complex reduces acetophenone to 1-phenylethanol in 94.7% ee. © 1994. | |
| dc.identifier.citation | Tetrahedron. v.50(21) | |
| dc.identifier.issn | 00404020 | |
| dc.identifier.uri | 10.1016/S0040-4020(01)80657-8 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0040402001806578 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12566 | |
| dc.title | Convenient procedures for the asymmetric reductions utilizing α,α-diphenyl- pyrrolidinemethanol and borane complexes generated using the I < inf > 2 < /inf > /NaBH < inf > 4 < /inf > system | |
| dc.type | Journal. Article | |
| dspace.entity.type |
Files
License bundle
1 - 1 of 1