Hard and soft-donors decorated rhenium based metallocavitands

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Date
2013-01-01
Authors
Rajakannu, Palanisamy
Elumalai, Palani
Mobin, Shaikh M.
Lu, Kuang Lieh
Sathiyendiran, Malaichamy
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Abstract
Flexible ligands containing two terminal mercaptobenzimidazolyl units were designed, synthesized, and utilized for metallocavitands in the presence of tetrahydroxybenzoquinone and R-2 (CO)10. These metallocavitands adopt unsymmetrical calix[4]arene-shaped frameworks, which contain two hydroxyl groups and two thioether units. © 2013 Elsevier B.V. All rights reserved.
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Keywords
Calixarene, Mercaptobenzimidazole, Metallocavitand, Rhenium/ Tetrahydroxybenzoquinone
Citation
Journal of Organometallic Chemistry. v.743