Methods for the synthesis of chiral sulfur heterocycles and their application in the asymmetric Baylis-Hillman reactions
Methods for the synthesis of chiral sulfur heterocycles and their application in the asymmetric Baylis-Hillman reactions
| dc.contributor.author | Periasamy, Mariappan | |
| dc.contributor.author | Gurubrahamam, Ramani | |
| dc.contributor.author | Muthukumaragopal, Gopal P. | |
| dc.date.accessioned | 2022-03-27T09:07:03Z | |
| dc.date.available | 2022-03-27T09:07:03Z | |
| dc.date.issued | 2013-05-31 | |
| dc.description.abstract | Enantiomerically pure (2S,6S)-2,6-diphenyltetrahydro-2H-thiopyran, (2S)-2-phenyltetrahydro thiophene, and (2S)-2-phenyltetrahydro-2H-thiopyran were prepared in 70-72% yields and with 86-99% ee via cyclization of the corresponding dimesylate in an SN2 cyclization reaction using sodium sulfide nonahydrate. The results on the application of various chiral sulfides in asymmetric Baylis-Hillman reactions are also described. © 2013 Elsevier Ltd. All rights reserved. | |
| dc.identifier.citation | Tetrahedron Asymmetry. v.24(9-10) | |
| dc.identifier.issn | 09574166 | |
| dc.identifier.uri | 10.1016/j.tetasy.2013.03.021 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0957416613001432 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12442 | |
| dc.title | Methods for the synthesis of chiral sulfur heterocycles and their application in the asymmetric Baylis-Hillman reactions | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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