Inter-conversion of 1-D coordination polymers in the Ce-Sr-dipicH  < inf > 2 < /inf >  system (dipicH < inf > 2 < /inf >  = dipicolinic acid)

dc.contributor.author	Prasad, T. K.
dc.contributor.author	Rajasekharan, M. V.
dc.date.accessioned	2022-03-27T09:16:27Z
dc.date.available	2022-03-27T09:16:27Z
dc.date.issued	2005-12-01
dc.description.abstract	A solution of the previously known 1-D coordination polymer, made up of alternating [Ce(dipic)3]2- and [Sr(dipicH 2)(OH2)3]2+ polyhedra takes up additional Ce4+ and Sr2+ ions leading to the double stranded hetero-metallic squarate chain. The transformation can be reversed by adding excess dipicH2. The crystal structure and thermal decomposition study of the new squarate chain polymer is reported. The analogous Ca compound does not undergo this transformation. © 2005 Elsevier B.V. All rights reserved.
dc.identifier.citation	Inorganic Chemistry Communications. v.8(12)
dc.identifier.issn	13877003
dc.identifier.uri	10.1016/j.inoche.2005.09.019
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/S1387700305002959
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/12682
dc.subject	Cerium(IV)
dc.subject	Crystal structure
dc.subject	Hetero-metallic coordination polymer
dc.subject	Inter-conversions
dc.subject	Strontium(II)
dc.title	Inter-conversion of 1-D coordination polymers in the Ce-Sr-dipicH < inf > 2 < /inf > system (dipicH < inf > 2 < /inf > = dipicolinic acid)
dc.type	Journal. Article
dspace.entity.type

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