A General and Stereospecific Synthesis of Trans Alkenes and Regiospecific Synthesis of Ketones via Stepwise Hydroboration
A General and Stereospecific Synthesis of Trans Alkenes and Regiospecific Synthesis of Ketones via Stepwise Hydroboration
| dc.contributor.author | Brown, Herbert C. | |
| dc.contributor.author | Basavaiah, D. | |
| dc.contributor.author | Kulkarni, Surendra U. | |
| dc.date.accessioned | 2022-03-27T09:06:15Z | |
| dc.date.available | 2022-03-27T09:06:15Z | |
| dc.date.issued | 1982-01-01 | |
| dc.description.abstract | The hydroboration of 1-bromo-1-alkynes with alkylbromoboranes (RBHBr·SMe2), conveniently obtained via the controlled hydridation of alkyldibromoboranes (RBBr2·SMe2), followed by treatment with sodium methoxide produces B-(trans-1-alkyl-1-alkenyl)boronate esters that provide the corresponding trans alkenes on protonolysis and ketones on oxidation. © 1982, American Chemical Society. All rights reserved. | |
| dc.identifier.citation | Journal of Organic Chemistry. v.47(19) | |
| dc.identifier.issn | 00223263 | |
| dc.identifier.uri | 10.1021/jo00140a056 | |
| dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/jo00140a056 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12420 | |
| dc.title | A General and Stereospecific Synthesis of Trans Alkenes and Regiospecific Synthesis of Ketones via Stepwise Hydroboration | |
| dc.type | Journal. Letter | |
| dspace.entity.type |
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