Synthesis of 3,8,13,18-tetrachloro-2,7,12,17-tetramethoxyporphyrin
Synthesis of 3,8,13,18-tetrachloro-2,7,12,17-tetramethoxyporphyrin
| dc.contributor.author | Rana, Anup | |
| dc.contributor.author | Panda, Pradeepta K. | |
| dc.date.accessioned | 2022-03-27T08:38:30Z | |
| dc.date.available | 2022-03-27T08:38:30Z | |
| dc.date.issued | 2011-05-25 | |
| dc.description.abstract | Vilsmeier-Haack formylation of 3,4-dimethoxypyrrole led to the unprecedented formation of 3-chloro-4-methoxypyrrole-2-aldehyde instead of the desired dialdehyde. Subsequent reduction and acid catalyzed cyclization led to the formation of type I, 3,8,13,18-tetrachloro-2,7,12,17-tetramethoxyporphyrin in approximately 6% yield. © 2011 Elsevier Ltd. All rights reserved. | |
| dc.identifier.citation | Tetrahedron Letters. v.52(21) | |
| dc.identifier.issn | 00404039 | |
| dc.identifier.uri | 10.1016/j.tetlet.2011.03.071 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0040403911004606 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11329 | |
| dc.subject | β-Tetrachlorotetramethoxyporphyrin | |
| dc.subject | 3,4-Dimethoxypyrrole | |
| dc.subject | 3-Chloro-4-methoxypyrrole-2- aldehyde | |
| dc.subject | Asymmetric pyrrole | |
| dc.subject | Vilsmeier-Haack formylation of pyrrole | |
| dc.title | Synthesis of 3,8,13,18-tetrachloro-2,7,12,17-tetramethoxyporphyrin | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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