Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes: An entry to tetraorganosilicon reagents for the silicon-based cross-coupling reaction
Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes: An entry to tetraorganosilicon reagents for the silicon-based cross-coupling reaction
| dc.contributor.author | Nakao, Yoshiaki | |
| dc.contributor.author | Imanaka, Hidekazu | |
| dc.contributor.author | Sahoo, Akhila K. | |
| dc.contributor.author | Yada, Akira | |
| dc.contributor.author | Hiyama, Tamejiro | |
| dc.date.accessioned | 2022-03-27T08:35:32Z | |
| dc.date.available | 2022-03-27T08:35:32Z | |
| dc.date.issued | 2005-05-18 | |
| dc.description.abstract | Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes, highly stable tetraorganosilicon reagents, are found to react with aryl and alkenyl iodides in the presence of a palladium catalyst and K2CO3 as a base, significantly milder conditions compared with those ever reported for the silicon-based cross-coupling reactions. The reaction tolerates a wide range of functional groups, including silyl protectors, and allows a gram-scale synthesis to recover and reuse the silicon residue. Copyright © 2005 American Chemical Society. | |
| dc.identifier.citation | Journal of the American Chemical Society. v.127(19) | |
| dc.identifier.issn | 00027863 | |
| dc.identifier.uri | 10.1021/ja051281j | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ja051281j | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11082 | |
| dc.title | Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes: An entry to tetraorganosilicon reagents for the silicon-based cross-coupling reaction | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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