Stereoselective synthesis of α,β-unsaturated carboxylic acids from alkynes using the Fe(CO) < inf > 5 < /inf > /t-BuOK/AcOH/CH < inf > 2 < /inf > Cl < inf > 2 < /inf > reagent system
Stereoselective synthesis of α,β-unsaturated carboxylic acids from alkynes using the Fe(CO) < inf > 5 < /inf > /t-BuOK/AcOH/CH < inf > 2 < /inf > Cl < inf > 2 < /inf > reagent system
| dc.contributor.author | Beesu, Mallesh | |
| dc.contributor.author | Periasamy, Mariappan | |
| dc.date.accessioned | 2022-03-27T09:07:19Z | |
| dc.date.available | 2022-03-27T09:07:19Z | |
| dc.date.issued | 2012-05-15 | |
| dc.description.abstract | Reactive iron carbonyl species generated in situ using the Fe(CO) 5/t-BuOK/CH 3COOH/CH 2Cl 2 reagent system reacts with alkynes to give the corresponding α,β-unsaturated carboxylic acids after CuCl 2·2H 2O oxidation with some regio and stereoselectivity. © 2012 Elsevier B.V. All rights reserved. | |
| dc.identifier.citation | Journal of Organometallic Chemistry. v.705 | |
| dc.identifier.issn | 0022328X | |
| dc.identifier.uri | 10.1016/j.jorganchem.2012.01.005 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0022328X12000204 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12449 | |
| dc.subject | α,β-Unsaturated carboxylic acids | |
| dc.subject | Alkynes | |
| dc.subject | Hydrocarboxylation | |
| dc.subject | Iron carbonyls | |
| dc.title | Stereoselective synthesis of α,β-unsaturated carboxylic acids from alkynes using the Fe(CO) < inf > 5 < /inf > /t-BuOK/AcOH/CH < inf > 2 < /inf > Cl < inf > 2 < /inf > reagent system | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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