A cubic 3d-4f structure with only ferromagnetic Gd-Mn interactions
A cubic 3d-4f structure with only ferromagnetic Gd-Mn interactions
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Date
2007-07-02
Authors
Prasad, Thazhe K.
Rajasekharan, Melath V.
Costes, Jean Pierre
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Journal ISSN
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Abstract
(Figure Presented) All aligned: A cubic 3d5-4f7 network of Mn2+ and Gd3+ ions is assembled by oxydiacetate (O(CH2CO2-)2). The network, which is reminiscent of Prussian blue analogues (see picture; Gd coordination polyhedra: purple, Mn coordination polyhedra: blue, [Mn(H2O) 6]2+: green, H2O: red), has a weak but definite ferromagnetic interaction. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
Description
Keywords
3d-4f networks,
Hybrid materials,
Lanthanides,
Magnetic properties,
Manganese
Citation
Angewandte Chemie - International Edition. v.46(16)