[Mn(acac) < inf > 2 < /inf > (HOCH < inf > 3 < /inf > ) < inf > 2 < /inf > ] < inf > 3 < /inf > [Ce(NO  < inf > 3 < /inf > ) < inf > 6 < /inf > ]-Icosahedral anion builds a cubic network

dc.contributor.author	Biju, A. R.
dc.contributor.author	Rajasekharan, M. V.
dc.date.accessioned	2022-03-27T09:15:42Z
dc.date.available	2022-03-27T09:15:42Z
dc.date.issued	2010-01-06
dc.description.abstract	Oxidation of Mn(II) in aqueous solution by ammonium eerie nitrate in the presence of acetylacetone (acacH) followed by subsequent crystallization from methanol leads to [Mn(acac)2(HOCH3)2] 3[Ce(NO3)6] (1). The icosahedrally coordinated Ce(NO3)63- ion with six octahedrally disposed hydrogen bond acceptor sites links the cations into a hydrogen bonded α-polonium-like network with a 2-fold parallel interpenetration. © 2009 American Chemical Society.
dc.identifier.citation	Crystal Growth and Design. v.10(1)
dc.identifier.issn	15287483
dc.identifier.uri	10.1021/cg901027c
dc.identifier.uri	https://pubs.acs.org/doi/10.1021/cg901027c
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/12664
dc.title	[Mn(acac) < inf > 2 < /inf > (HOCH < inf > 3 < /inf > ) < inf > 2 < /inf > ] < inf > 3 < /inf > [Ce(NO < inf > 3 < /inf > ) < inf > 6 < /inf > ]-Icosahedral anion builds a cubic network
dc.type	Journal. Article
dspace.entity.type

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