A trigonal prismatic Mn(II) complex, [MnL(H < inf > 2 < /inf > O)] < sup > 2+ < /sup > , with bis(picolinylidenehydrazyl)(2-pyridyl)methane (L). Synthesis, structure and properties
A trigonal prismatic Mn(II) complex, [MnL(H < inf > 2 < /inf > O)] < sup > 2+ < /sup > , with bis(picolinylidenehydrazyl)(2-pyridyl)methane (L). Synthesis, structure and properties
| dc.contributor.author | Gupta Sreerama, Subramanya | |
| dc.contributor.author | Pal, Satyanarayan | |
| dc.contributor.author | Pal, Samudranil | |
| dc.date.accessioned | 2022-03-27T08:47:46Z | |
| dc.date.available | 2022-03-27T08:47:46Z | |
| dc.date.issued | 2001-10-29 | |
| dc.description.abstract | The complex, [MnL(H2O)]2+, has been isolated by the reaction of N,N′-bis(picolinylidene)hydrazine with N-(picolinylidene)hydrazine in presence of Mn2+. The pentadentate N5 donor ligand, bis(picolinylidenehydrazyl)(2-pyridyl)methane (L), is formed by the addition of N-(picolinylidene)hydrazine to one of the metal activated azomethine fragment of the tetradentate diazine ligand N, N′-bis(picolinylidene)hydrazine. The X-ray structure reveals the trigonal prismatic N5O coordination geometry around the high-spin metal centre in [MnL(H2O)]2+. © 2001 Elsevier Science B.V. All rights reserved. | |
| dc.identifier.citation | Inorganic Chemistry Communications. v.4(11) | |
| dc.identifier.issn | 13877003 | |
| dc.identifier.uri | 10.1016/S1387-7003(01)00302-1 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S1387700301003021 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11805 | |
| dc.subject | Manganese(II) complex | |
| dc.subject | Pentadentate ligand | |
| dc.subject | Trigonal prism | |
| dc.subject | X-ray structure | |
| dc.title | A trigonal prismatic Mn(II) complex, [MnL(H < inf > 2 < /inf > O)] < sup > 2+ < /sup > , with bis(picolinylidenehydrazyl)(2-pyridyl)methane (L). Synthesis, structure and properties | |
| dc.type | Journal. Article | |
| dspace.entity.type |
Files
License bundle
1 - 1 of 1