Applications of the baylis-hillman adducts in organic synthesis: A facile synthesis of [E]-α-cyanocinnamyl alcohols and [E]-α-cyanocinnamic aldehydes

dc.contributor.author	Basavaiah, Deevi
dc.contributor.author	Kumaragurubaran, Nagaswamy
dc.contributor.author	Padmaja, Kisari
dc.date.accessioned	2022-03-27T09:03:47Z
dc.date.available	2022-03-27T09:03:47Z
dc.date.issued	1999-01-01
dc.description.abstract	Aqueous sulfuric acid mediated transformation of the Baylis-Hillman adducts, i.e. 3-aryl-3-hydroxy-2-methylenepropanenitriles, into [E]-α- cyanocinnamyl alcohols and subsequent oxidation with PCC leading to the formation of stereochemically pure [E]-α-cyanocinnamic aldehydes, which represents an efficient alternative route to the Knoevenagel condensation reaction, is described.
dc.identifier.citation	Synlett
dc.identifier.issn	09365214
dc.identifier.uri	10.1055/s-1999-2893
dc.identifier.uri	http://www.thieme-connect.de/DOI/DOI?10.1055/s-1999-2893
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/12353
dc.subject	And oxidation
dc.subject	Baylis-Hillman reaction
dc.subject	Isomerization
dc.subject	[E]-α- cyanocinnamic aldehydes
dc.subject	[E]-α-cyanocinnamyl alcohols
dc.title	Applications of the baylis-hillman adducts in organic synthesis: A facile synthesis of [E]-α-cyanocinnamyl alcohols and [E]-α-cyanocinnamic aldehydes
dc.type	Journal. Article
dspace.entity.type

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