A mononuclear manganese (III) schiff base complex, [Mn(C < inf > 14 < /inf > H < inf > 10 < /inf > N < inf > 2 < /inf > O < inf > 2 < /inf > )-(C < inf > 8 < /inf > H < inf > 7 < /inf > O < inf > 3 < /inf > )(CH < inf > 1 < /inf > O)]

dc.contributor.author	Dutta, Somnath
dc.contributor.author	Manivannan, Vadivelu
dc.contributor.author	Babu, Lingamallu Giri
dc.contributor.author	Pal, Samudranil
dc.date.accessioned	2022-03-27T08:48:21Z
dc.date.available	2022-03-27T08:48:21Z
dc.date.issued	1995-05-15
dc.description.abstract	In the title compound, [2-(α-hydroxybenzylidene-hydrazonomethyl)phenolato(2-)-N,O,O′](methanol-0)-(methyl salicylato-0,O′)rnanganese(III), [Mn(BHS)-(MS)(CH3OH)], the manganese(III) ion is surrounded by an O5N coordination sphere. The tridentate 2-(α-hydroxybenzylidenehydrazonomethyl)phenol-ate (BHS2-) ligand (H2BHS is the benzoyl hydrazone of salicylaldehyde) binds the metal ion meridionally and the methyl salicylate (MS-) ligand is bidentate. The sixth position is occupied by a methanol molecule. There is a significant tetragonal elongation due to a Jahn-Teller effect.
dc.identifier.citation	Acta Crystallographica Section C: Crystal Structure Communications. v.51(5)
dc.identifier.issn	01082701
dc.identifier.uri	10.1107/S0108270194012151
dc.identifier.uri	http://scripts.iucr.org/cgi-bin/paper?S0108270194012151
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11829
dc.title	A mononuclear manganese (III) schiff base complex, [Mn(C < inf > 14 < /inf > H < inf > 10 < /inf > N < inf > 2 < /inf > O < inf > 2 < /inf > )-(C < inf > 8 < /inf > H < inf > 7 < /inf > O < inf > 3 < /inf > )(CH < inf > 1 < /inf > O)]
dc.type	Journal. Article
dspace.entity.type

Now showing 1 - 1 of 1