Silver(I) based dinuclear metallacycles with free thiophenyl/thiomethyl units
Silver(I) based dinuclear metallacycles with free thiophenyl/thiomethyl units
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Date
2016-02-01
Authors
Yadav, Sarita
Gupta, Deepak
Sathiyendiran, Malaichamy
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Abstract
Three dinuclear, ionic and homoleptic metallacycles decorated with free thiophenyl or thiomethyl units were synthesized using AgOS(O 2)CF 3 and benzimidazole derived ditopic N-donor ligands at ambient condition. The complexes were characterized by analytical and spectroscopic (IR and 1H NMR) techniques and two of the complexes were structurally characterised through single crystal X-ray diffraction.
Description
Keywords
benzimidazole,
Metallacycle,
silver,
supramolecule,
thiomethyl,
thiophenyl
Citation
Journal of Chemical Sciences. v.128(2)