Influence of intermolecular interactions on coordination geometry - Crystal and molecular structure of Ag(dmp)NO < inf > 3 < /inf > • 2H < inf > 2 < /inf > O (dmp = 2,9-dimethyl-1,10-phenanthroline)
Influence of intermolecular interactions on coordination geometry - Crystal and molecular structure of Ag(dmp)NO < inf > 3 < /inf > • 2H < inf > 2 < /inf > O (dmp = 2,9-dimethyl-1,10-phenanthroline)
| dc.contributor.author | Swarnabala, G. | |
| dc.contributor.author | Rajasekharan, M. V. | |
| dc.date.accessioned | 2022-03-27T09:17:24Z | |
| dc.date.available | 2022-03-27T09:17:24Z | |
| dc.date.issued | 1996-01-01 | |
| dc.description.abstract | Non-bonded interactions stabilise a normal Ag(dmp)NO3 molecule and a highly distorted [Ag2(dmp)2NO3]+ in the crystal of Ag(dmp)NO3'2H2O. The structure consists of two complex molecules, a mononuclear Ag2(dmp)2NO3 and NO3 bridged dinuclear cation [Ag2(dmp)2NO3]+ . The coordination around Ag in Ag(dmp)NO3 is of a regular 3+1 type while the dinuclear cation has a highly distorted geometry. The ring-ring stacking, CH3 - CH3 interactions and C - H ⋯ O H-bonding stabilise the two complex molecules. Copyright © 1996 Elsevier Science Ltd. | |
| dc.identifier.citation | Polyhedron. v.15(19) | |
| dc.identifier.issn | 02775387 | |
| dc.identifier.uri | 10.1016/0277-5387(96)00064-2 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/0277538796000642 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12705 | |
| dc.title | Influence of intermolecular interactions on coordination geometry - Crystal and molecular structure of Ag(dmp)NO < inf > 3 < /inf > • 2H < inf > 2 < /inf > O (dmp = 2,9-dimethyl-1,10-phenanthroline) | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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