Cyclic oxyphosphoranes with six-and seven-membered rings
Cyclic oxyphosphoranes with six-and seven-membered rings
| dc.contributor.author | Kumara Swamy, K. C. | |
| dc.contributor.author | Burton, Sarah D. | |
| dc.contributor.author | Holmes, Joan M. | |
| dc.contributor.author | Day, Roberta O. | |
| dc.contributor.author | Holmes, Robert R. | |
| dc.date.accessioned | 2022-03-27T09:59:43Z | |
| dc.date.available | 2022-03-27T09:59:43Z | |
| dc.date.issued | 1990-05-01 | |
| dc.description.abstract | X-ray and variable temperature NMR investigations of cyclic pentaoxyphosphoranes reveal a preference of six-and seven-membered rings for apical-equatorial orientations of trigonal bipyramids. Saturated six-membered rings prefer a boat conformation. Apical-equatorial ring pseudorotations are more facile for five-membered rings, whereas ligand exchange via diequatorial ring placement is more facile for the larger rings. Application to enzymatic reactions of cyclic AMP is emphasized. © 1990, Taylor & Francis Group, LLC. All rights reserved. | |
| dc.identifier.citation | Phosphorus, Sulfur, and Silicon and the Related Elements. v.49-50(1-4) | |
| dc.identifier.issn | 10426507 | |
| dc.identifier.uri | 10.1080/10426509008038981 | |
| dc.identifier.uri | http://www.tandfonline.com/doi/abs/10.1080/10426509008038981 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13508 | |
| dc.title | Cyclic oxyphosphoranes with six-and seven-membered rings | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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