A chiral Mn(IV) complex and its supramolecular assembly: Synthesis, characterization and properties
A chiral Mn(IV) complex and its supramolecular assembly: Synthesis, characterization and properties
| dc.contributor.author | Pradeep, Chullikkattil P. | |
| dc.contributor.author | Zacharias, Panthapally S. | |
| dc.contributor.author | Das, Samar K. | |
| dc.date.accessioned | 2022-03-27T08:44:13Z | |
| dc.date.available | 2022-03-27T08:44:13Z | |
| dc.date.issued | 2006-07-01 | |
| dc.description.abstract | The open air reaction of the chiral Schiff base ligand H2L, prepared by the condensation of L-phenylalaninol and 5-bromosalicylaldehyde, with MnII(CH3COO)2·4H2O yielded dark brown complex [MnIVL2]·0·5 DMF (1). Compound 1 was characterized by elemental analysis, IR, UV-visible, CD and EPR spectroscopy, cyclic voltammetry and room temperature magnetic moment determination. Single-crystal X-ray analysis revealed that compound 1 crystallises in the monoclinic P21 space group with six mononuclear [MnIVL2] units in the asymmetric unit along with three solvent DMF molecules. In the crystal structure, each Mn(IV) complex, acting as the building unit, undergoes supramolecular linking through C-H⋯O bonds leading to an intricate hydrogen bonding network. © Indian Academy of Sciences. | |
| dc.identifier.citation | Journal of Chemical Sciences. v.118(4) | |
| dc.identifier.issn | 02534134 | |
| dc.identifier.uri | 10.1007/BF02708524 | |
| dc.identifier.uri | http://link.springer.com/10.1007/BF02708524 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11646 | |
| dc.subject | C-H⋯O hydrogen bonding interaction | |
| dc.subject | Characterization | |
| dc.subject | Chiral Mn(IV) complex | |
| dc.subject | Crystal structure | |
| dc.subject | Synthesis | |
| dc.title | A chiral Mn(IV) complex and its supramolecular assembly: Synthesis, characterization and properties | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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