Characterization of the first hexacoordinate phosphorus compound with S→P←S bonds

dc.contributor.author	Pavan Kumar, K. V.P.
dc.contributor.author	Phani Pavan, M.
dc.contributor.author	Kumara Swamy, K. C.
dc.date.accessioned	2022-03-27T09:52:24Z
dc.date.available	2022-03-27T09:52:24Z
dc.date.issued	2009-06-01
dc.description.abstract	The first example of a hexacoordinate phosphorus compound [S{6-t-Bu-4-Me-C6H2O}2]2P +(Cl-·C3H4N2) with two S→P bonds is reported. This compound can be construed as an oxophosphonium salt with double intramolecular coordination by sulfur atoms. X-ray structure reveals a facial arrangement of the ligands with two coordinating sulfur atoms cis to each other. The S→P distance of 2.334 (1) Å is one among very short coordinate bond distances between sulfur and phosphorus. © 2009 Elsevier B.V. All rights reserved.
dc.identifier.citation	Inorganic Chemistry Communications. v.12(6)
dc.identifier.issn	13877003
dc.identifier.uri	10.1016/j.inoche.2009.04.013
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/S1387700309002044
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/13392
dc.subject	Coordination geometry
dc.subject	Hypervalency
dc.subject	Phosphonium salt
dc.subject	Phosphorane
dc.subject	Structure
dc.title	Characterization of the first hexacoordinate phosphorus compound with S→P←S bonds
dc.type	Journal. Article
dspace.entity.type

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