Redox in a ferroverdin analogue: Recognition of isomeric co-ordination spheres by Fe < sup > II < /sup > and Fe < sup > III < /sup >
Redox in a ferroverdin analogue: Recognition of isomeric co-ordination spheres by Fe < sup > II < /sup > and Fe < sup > III < /sup >
No Thumbnail Available
Date
1989-01-01
Authors
Basu, Partha
Pal, Samudranil
Chakravorty, Animesh
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
The N3O3 co-ordination sphere of (1b) and (1c) selectively stabilises low-spin FeII and FeIII in fac (2a) and mer (2b) geometries, respectively; mismatched combinations generated by rapid chemical/electrochemical electron transfer at low temperatures undergo spontaneous isomerisation at measurable rates to achieve equilibrium populations.
Description
Keywords
Citation
Journal of the Chemical Society, Chemical Communications