Pheromone synthesis via organoboranes: A stereoselective synthesis of (E)-1,3-alkenynes via thexylchloroborane-dimethyl sulfide

dc.contributor.author Brown, Herbert C.
dc.contributor.author Bhat, N. G.
dc.contributor.author Basavaiah, D.
dc.date.accessioned 2022-03-27T09:05:45Z
dc.date.available 2022-03-27T09:05:45Z
dc.date.issued 1986-01-01
dc.description.abstract Treatment of thexylalkenylalkynylhoranes with iodine in the presence of potassium methoxide produces (E)-l,3-enynes in good yield (58-82%) and excellent stereochemical purities (≥95 %). The methodology was successfully applied to the synthesis of (5Z,7E)-5,7-dodeeadien-l-ol, the sex pheromone of the forest tent caterpillar (Malacosoma disstria).
dc.identifier.citation Synthesis (Germany). v.1986(8)
dc.identifier.issn 00397881
dc.identifier.uri 10.1055/s-1986-31746
dc.identifier.uri http://www.thieme-connect.de/DOI/DOI?10.1055/s-1986-31746
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/12406
dc.title Pheromone synthesis via organoboranes: A stereoselective synthesis of (E)-1,3-alkenynes via thexylchloroborane-dimethyl sulfide
dc.type Journal. Article
dspace.entity.type
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