A half-sandwich rhodium(III) complex with 4-bromo-N-(1-pyrenylidene)aniline: Regioselective cyclorhodation of the 1-pyrenyl group
A half-sandwich rhodium(III) complex with 4-bromo-N-(1-pyrenylidene)aniline: Regioselective cyclorhodation of the 1-pyrenyl group
| dc.contributor.author | Rao, A. R.Balavardhana | |
| dc.contributor.author | Babu, G. Narendra | |
| dc.contributor.author | Pal, Samudranil | |
| dc.date.accessioned | 2022-03-27T08:45:56Z | |
| dc.date.available | 2022-03-27T08:45:56Z | |
| dc.date.issued | 2015-10-02 | |
| dc.description.abstract | Reaction of [RhCp∗Cl2]2 (Cp∗ = pentamethylcyclopentadienyl anion), 4-bromo-N-(1-pyrenylidene)aniline (Hpyan, H represents a proton of the 1-pyrenyl ring) and CH3CO2Na in 1:2:6 mole ratio in dichloromethane provides the half-sandwich, cyclometallated rhodium(III) complex [RhCp∗(pyan)Cl]. X-ray crystallographic study confirms the bidentate 1-pyrenyl ortho-C and azomethine-N coordination mode of (pyan)- and the half-sandwich 'piano-stool' structure of [RhCp∗(pyan)Cl]. In dichloromethane, the diamagnetic, redox active complex displays a metal-centred oxidation at E1/2 = 1.14 V (versus Ag/AgCl). | |
| dc.identifier.citation | Journal of Chemical Research. v.39(10) | |
| dc.identifier.issn | 17475198 | |
| dc.identifier.uri | 10.3184/174751915X14416979694082 | |
| dc.identifier.uri | http://journals.sagepub.com/doi/10.3184/174751915X14416979694082 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11727 | |
| dc.subject | Crystal structure | |
| dc.subject | Half-sandwich | |
| dc.subject | Ortho-metallation | |
| dc.subject | Redox property | |
| dc.subject | Rhodium(III) | |
| dc.title | A half-sandwich rhodium(III) complex with 4-bromo-N-(1-pyrenylidene)aniline: Regioselective cyclorhodation of the 1-pyrenyl group | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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