Triazabicyclodecene as an Organocatalyst for the Regiospecific Synthesis of 1,4,5-Trisubstituted N-Vinyl-1,2,3-triazoles

dc.contributor.author	Ramachary, Dhevalapally B.
dc.contributor.author	Gujral, Jagjeet
dc.contributor.author	Peraka, Swamy
dc.contributor.author	Reddy, G. Surendra
dc.date.accessioned	2022-03-27T09:38:33Z
dc.date.available	2022-03-27T09:38:33Z
dc.date.issued	2017-01-18
dc.description.abstract	Herein we report on the 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) catalyzed enolate-mediated regiospecific synthesis of 1,4,5-trisubstituted N-vinyl-1,2,3-triazoles from simple activated carbonyl compounds and N-vinyl azides through [3+2] cycloaddition; upon further hydrogenation, 1,4,5-trisubstituted N-alkyl-1,2,3-triazoles are furnished. Both the organo-click and hydrogenation reactions proceeded in excellent yields with high rates and selectivities at 25 °C within a few hours.
dc.identifier.citation	European Journal of Organic Chemistry. v.2017(3)
dc.identifier.issn	1434193X
dc.identifier.uri	10.1002/ejoc.201601497
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/ejoc.201601497
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/13147
dc.subject	Azides
dc.subject	Click chemistry
dc.subject	Cycloaddition
dc.subject	Nitrogen heterocycles
dc.subject	Organocatalysis
dc.title	Triazabicyclodecene as an Organocatalyst for the Regiospecific Synthesis of 1,4,5-Trisubstituted N-Vinyl-1,2,3-triazoles
dc.type	Journal. Article
dspace.entity.type

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