Bismuth and Titanium Phosphinates: Isolation of Tetra-, Hexa- A nd Octanuclear Clusters
Bismuth and Titanium Phosphinates: Isolation of Tetra-, Hexa- A nd Octanuclear Clusters
| dc.contributor.author | Ali, Junaid | |
| dc.contributor.author | Navaneetha, Tokala | |
| dc.contributor.author | Baskar, Viswanathan | |
| dc.date.accessioned | 2022-03-27T08:59:18Z | |
| dc.date.available | 2022-03-27T08:59:18Z | |
| dc.date.issued | 2020-01-06 | |
| dc.description.abstract | The reaction of organobismuth precursors with trityl-H-phosphinic acid in varying reaction conditions afforded colorless crystals, whose single crystal X-ray characterization revealed the formation of monomer {(Ph3Bi)[(Ph3C)(H)PO2]2}·3/2(CH3CN)21/2H2O (1) and butterfly shaped tetranuclear cluster Bi4(μ3-O)2[(Ph3C)(H)(PO2)]8·2CH2Cl2·1/2CH3CN.2H2O (2). The reaction of titanium isopropoxide with two different phosphinic acids trityl-H-phosphinic acid and cycP(O)(OH) led to isolation of cubane type octahedral complex {Ti8(μ2-O)8(μ2-OH)4[(Ph3C)(H)PO2]12}[3C7H8] (3) and hexanuclear complex Ti6(μ2-cycPO2)9(μ2-O)6(μ2-OH)3·4CH3CN·4H2O (4) respectively. | |
| dc.identifier.citation | Inorganic Chemistry. v.59(1) | |
| dc.identifier.issn | 00201669 | |
| dc.identifier.uri | 10.1021/acs.inorgchem.9b02960 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b02960 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12218 | |
| dc.title | Bismuth and Titanium Phosphinates: Isolation of Tetra-, Hexa- A nd Octanuclear Clusters | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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