Copper(II) complexes with chiral reduced Schiff bases: Helical self-assembly via intermolecular C-H⋯O interactions

dc.contributor.author Muppidi, Vamsee Krishna
dc.contributor.author Das, Sunirban
dc.contributor.author Raghavaiah, Pallepogu
dc.contributor.author Pal, Samudranil
dc.date.accessioned 2022-03-27T08:46:53Z
dc.date.available 2022-03-27T08:46:53Z
dc.date.issued 2007-02-01
dc.description.abstract Copper(II) complexes having the general formula [Cu(Ln)2] with the N,O-donor reduced Schiff bases N-(2-hydroxy-5-X-benzyl)-(R)-α-methylbenzylamine and N-(2-hydroxy-5-X-benzyl)-(S)-α-methylbenzylamine (X = Cl and Br) (HLn) are described. These chiral complexes crystallize in the noncentrosymmetric P212121 (X = Cl) and P21 (X = Br) space groups. In each case, self-assembly via intermolecular C-H⋯O interaction leads to a supramolecular helical superstructure. © 2006 Elsevier B.V. All rights reserved.
dc.identifier.citation Inorganic Chemistry Communications. v.10(2)
dc.identifier.issn 13877003
dc.identifier.uri 10.1016/j.inoche.2006.10.011
dc.identifier.uri https://www.sciencedirect.com/science/article/abs/pii/S1387700306003959
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/11768
dc.subject Chiral
dc.subject Copper(II) complexes
dc.subject Crystal structures
dc.subject Helical self-assembly
dc.subject Reduced schiff bases
dc.title Copper(II) complexes with chiral reduced Schiff bases: Helical self-assembly via intermolecular C-H⋯O interactions
dc.type Journal. Article
dspace.entity.type
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