Stereoselective synthesis of C < inf > 18 < /inf > -guggultetrol and C < inf > 18 < /inf > -phytosphingosine analogues from d-fructose

dc.contributor.author Ramu Sridhar, Perali
dc.contributor.author Suresh, Mandava
dc.contributor.author Venu Kumar, Patteti
dc.contributor.author Seshadri, Kalapati
dc.contributor.author Venkata Rao, Chunduri
dc.date.accessioned 2022-03-27T08:37:37Z
dc.date.available 2022-03-27T08:37:37Z
dc.date.issued 2012-10-01
dc.description.abstract A series of C 18-guggultetrol stereo isomers and C 18-phytosphingosine regio/stereo isomers were synthesised in a stereoselective fashion involving metal mediated fragmentation, stereoselective reduction, 1,4 O→O silyl migration, and Grubbs' cross metathesis as key steps. d-Fructose was used as a raw material for the preparation of all the analogues. The isophytosphingosine derivatives were evaluated against their 5-LOX (5-lipoxigenase) inhibitory activity. © 2012 Elsevier Ltd. All rights reserved.
dc.identifier.citation Carbohydrate Research. v.360
dc.identifier.issn 00086215
dc.identifier.uri 10.1016/j.carres.2012.07.016
dc.identifier.uri https://www.sciencedirect.com/science/article/abs/pii/S0008621512003084
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/11266
dc.subject 5-Lipoxigenase
dc.subject C -Guggultetrol 18
dc.subject d-Fructose
dc.subject Isophytosphingosine
dc.subject Phytosphingosine
dc.title Stereoselective synthesis of C < inf > 18 < /inf > -guggultetrol and C < inf > 18 < /inf > -phytosphingosine analogues from d-fructose
dc.type Journal. Article
dspace.entity.type
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