Assembling nanosized ring-shaped synthons to an anionic layer structure based on the synergetically induced functional complementarity of their surface-sites
Assembling nanosized ring-shaped synthons to an anionic layer structure based on the synergetically induced functional complementarity of their surface-sites
| dc.contributor.author | Müller, Achim | |
| dc.contributor.author | Das, Samar K. | |
| dc.contributor.author | Bögge, Hartmut | |
| dc.contributor.author | Beugholt, Christian | |
| dc.contributor.author | Schmidtmann, Marc | |
| dc.date.accessioned | 2022-03-27T08:45:04Z | |
| dc.date.available | 2022-03-27T08:45:04Z | |
| dc.date.issued | 1999-06-07 | |
| dc.description.abstract | The reaction of an aqueous solution of sodium molybdate with hypophosphorous (phosphinic) acid acting both as reducing agent and ligand at low pH values (≃ 1) results in the formation of nanosized ring-shaped cluster units which assemble to form layers of the compound Na21[Mo(VI)126-Mo(V)28O462H14 (H2O)54(H2PO2)7].xH2O 1 (x ≃ 300); the assemblage is based on the synergetically induced functional complementarity of amphiphilic O = MoL (L = H2O, H2PO2-) groups and corresponds to the replacement of H2O ligands of rings by related terminal Mo = O groups of other rings (and vice versa) the nucleophilicity of which is induced by coordinated H2PO2- ligands. | |
| dc.identifier.citation | Chemical Communications | |
| dc.identifier.issn | 13597345 | |
| dc.identifier.uri | 10.1039/a901562k | |
| dc.identifier.uri | http://xlink.rsc.org/?DOI=a901562k | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11688 | |
| dc.title | Assembling nanosized ring-shaped synthons to an anionic layer structure based on the synergetically induced functional complementarity of their surface-sites | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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