Enantioselective synthesis of 2,3-diphenyl-1,4-butanediol via oxidative coupling of phenylacetic acid chiral 1,1'-bi-2-naphthyl ester using TiCl < inf > 4 < /inf > /Et < inf > 3 < /inf > N
Enantioselective synthesis of 2,3-diphenyl-1,4-butanediol via oxidative coupling of phenylacetic acid chiral 1,1'-bi-2-naphthyl ester using TiCl < inf > 4 < /inf > /Et < inf > 3 < /inf > N
| dc.contributor.author | Rao, Vutukuri Dharma | |
| dc.contributor.author | Periasamy, Mariappan | |
| dc.date.accessioned | 2022-03-27T09:10:30Z | |
| dc.date.available | 2022-03-27T09:10:30Z | |
| dc.date.issued | 1999-03-24 | |
| dc.description.abstract | Oxidative coupling of phenylacetic acid ester of homochiral 1,1'-bi-2-naphthol 2 was achieved by reaction with TiCl4/Et3N to obtain the corresponding 2,3-diphenylsuccinic acid derivative 3, which on reduction using the NaBH4/I2 reagent gives homochiral 2,3-diphenyl-1,4-butanediol. X-Ray structural analysis was carried out for the compounds (R)-(+)-2 and (R,R,R)-(-)-3. Copyright (C) 2000. | |
| dc.identifier.citation | Tetrahedron Asymmetry. v.11(5) | |
| dc.identifier.issn | 09574166 | |
| dc.identifier.uri | 10.1016/S0957-4166(00)00040-9 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0957416600000409 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12534 | |
| dc.title | Enantioselective synthesis of 2,3-diphenyl-1,4-butanediol via oxidative coupling of phenylacetic acid chiral 1,1'-bi-2-naphthyl ester using TiCl < inf > 4 < /inf > /Et < inf > 3 < /inf > N | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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