Transformable Sulfoximine Assisted One-Pot Double Annulation of Vinylic C-H Bonds with Unactivated Alkynes
Transformable Sulfoximine Assisted One-Pot Double Annulation of Vinylic C-H Bonds with Unactivated Alkynes
| dc.contributor.author | Shankar, Majji | |
| dc.contributor.author | Guntreddi, Tirumaleswararao | |
| dc.contributor.author | Ramesh, E. | |
| dc.contributor.author | Sahoo, Akhila K. | |
| dc.date.accessioned | 2022-03-27T09:52:38Z | |
| dc.date.available | 2022-03-27T09:52:38Z | |
| dc.date.issued | 2017-10-20 | |
| dc.description.abstract | The methylphenyl sulfoximine (MPS) directing group (DG) successfully promotes the one-pot double annulation of acrylic acids with alkynes under Ru catalysis, which is unprecedented. Diverse arrays of pyrido-fused-isoquinolinone skeletons are fabricated from acrylamides, creating two C-C and two C-N bonds in a single operation. The unsymmetrical annulation with two distinct alkynes is presented. The recovery of methylphenyl sulfoxide, a precursor of MPS, validates the synthetic adaptability of transformable-DG (TfDG) in C-H activation. | |
| dc.identifier.citation | Organic Letters. v.19(20) | |
| dc.identifier.issn | 15237060 | |
| dc.identifier.uri | 10.1021/acs.orglett.7b02824 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.orglett.7b02824 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13396 | |
| dc.title | Transformable Sulfoximine Assisted One-Pot Double Annulation of Vinylic C-H Bonds with Unactivated Alkynes | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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