New Methods of Resolution and Enrichment of Enantiomeric Excesses of 1,1′-Bi-2-naphthol
New Methods of Resolution and Enrichment of Enantiomeric Excesses of 1,1′-Bi-2-naphthol
| dc.contributor.author | Periasamy, Mariappan | |
| dc.contributor.author | Venkatraman, Lakshmanan | |
| dc.contributor.author | Justin Thomas, K. R. | |
| dc.date.accessioned | 2022-03-27T09:11:04Z | |
| dc.date.available | 2022-03-27T09:11:04Z | |
| dc.date.issued | 1997-01-01 | |
| dc.description.abstract | Partial resolution of racemic 1,1′-bi-2-naphthol (1) was readily achieved to obtain enriched (scalemic) 1 using (S)-proline (2), The structure of the complex 3 formed between 1 (2 equiv) and (S)-proline (1 equiv) was characterized by an X-ray diffraction method. Enantiomeric excesses of the incompletely resolved 1 were enriched to obtain essentially pure (R)- and (S)-1 following a simple procedure using B(OH)3 and TMEDA. | |
| dc.identifier.citation | Journal of Organic Chemistry. v.62(13) | |
| dc.identifier.issn | 00223263 | |
| dc.identifier.uri | 10.1021/jo961937e | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/jo961937e | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12549 | |
| dc.title | New Methods of Resolution and Enrichment of Enantiomeric Excesses of 1,1′-Bi-2-naphthol | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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