Direct organocatalytic in situ generation of novel push-pull dienamines: Application in tandem Claisen-Schmidt/iso-aromatization reactions

dc.contributor.author	Ramachary, Dhevalapally B.
dc.contributor.author	Ramakumar, K.
dc.contributor.author	Kishor, M.
dc.date.accessioned	2022-03-27T09:42:24Z
dc.date.available	2022-03-27T09:42:24Z
dc.date.issued	2005-10-10
dc.description.abstract	A new, green, regioselective, one-step, tandem reaction of an aldehyde possessing a non-enolizable carbonyl function with a highly substituted cyclohex-2-enone, under amine catalysis afforded highly substituted phenols or 2-arylidenecyclohexanones, respectively. The yields and regioselectivities were good. Evidence for a pathway involving formation of novel push-pull dienamines is presented along with examples demonstrating the amenability of the process to combinatorial chemistry. © 2005 Elsevier Ltd. All rights reserved.
dc.identifier.citation	Tetrahedron Letters. v.46(41)
dc.identifier.issn	00404039
dc.identifier.uri	10.1016/j.tetlet.2005.08.051
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/S0040403905017855
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/13218
dc.subject	Amines
dc.subject	Hagemann's ester
dc.subject	Organocatalysis
dc.subject	Push-pull dienamine
dc.subject	Tandem reactions
dc.title	Direct organocatalytic in situ generation of novel push-pull dienamines: Application in tandem Claisen-Schmidt/iso-aromatization reactions
dc.type	Journal. Article
dspace.entity.type

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