A water pipe held up by a polyoxometalate supported transition metal complex: Synthesis and characterization of [Cu < inf > 2 < /inf > (phen) < inf > 2 < /inf > (CH < inf > 3 < /inf > COO)-(CH < inf > 3 < /inf > COOH)(H < inf > 2 < /inf > O) < inf > 2 < /inf > ][Al(OH) < inf > 6 < /inf > Mo < inf > 6 < /inf > O < inf > 18 < /inf > ]·28H < inf > 2 < /inf > O
A water pipe held up by a polyoxometalate supported transition metal complex: Synthesis and characterization of [Cu < inf > 2 < /inf > (phen) < inf > 2 < /inf > (CH < inf > 3 < /inf > COO)-(CH < inf > 3 < /inf > COOH)(H < inf > 2 < /inf > O) < inf > 2 < /inf > ][Al(OH) < inf > 6 < /inf > Mo < inf > 6 < /inf > O < inf > 18 < /inf > ]·28H < inf > 2 < /inf > O
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Date
2007-01-30
Authors
Shivaiah, Vaddypally
Chatterjee, Tanmay
Srinivasu, Khandregula
Das, Samar K.
Journal Title
Journal ISSN
Volume Title
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Abstract
A water pipe, formed exclusively from lattice water molecules, is stabilized in an organic-inorganic hybrid material Cu2(phen) 2(CH3COO)(CH3COOH) (H2O) 2][Al(OH)6Mo6O18]·28H 2O (1). Compound 1 consists of an Anderson-type heteropolyanion, a copper acetate dimer, and 28 lattice water molecules. Once the relevant crystal is removed from the mother liquor it loses water molecules, which results in the demolition of the water pipe. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
Description
Keywords
Copper acetate dimer,
Crystal structure,
Heteropolyanion,
Hydrogen bonds,
Lattice waters,
Supramolecular chemistry
Citation
European Journal of Inorganic Chemistry